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Journal Articles

Conceptual design of the iodine-sulfur process flowsheet with more than 50% thermal efficiency for hydrogen production

Kasahara, Seiji; Imai, Yoshiyuki; Suzuki, Koichi*; Iwatsuki, Jin; Terada, Atsuhiko; Yan, X.

Nuclear Engineering and Design, 329, p.213 - 222, 2018/04

 Times Cited Count:21 Percentile:91.03(Nuclear Science & Technology)

A conceptual design of a practical large scale plant of the thermochemical water splitting iodine-sulfur (IS) process flowsheet was carried out as a heat application of JAEA's commercial high temperature gas cooled reactor GTHTR300C plant design. Innovative techniques proposed by JAEA were applied for improvement of hydrogen production thermal efficiency; depressurized flash concentration H$$_{2}$$SO$$_{4}$$ using waste heat from Bunsen reaction, prevention of H$$_{2}$$SO$$_{4}$$ vaporization from a distillation column by introduction of H$$_{2}$$SO$$_{4}$$ solution from a flash bottom, and I$$_{2}$$ condensation heat recovery in an HI distillation column. Hydrogen of about 31,900 Nm$$^{3}$$/h would be produced by 170 MW heat from the GTHTR300C. A thermal efficiency of 50.2% would be achievable with incorporation of the innovative techniques and high performance HI concentration and decomposition components and heat exchangers expected in future R&D.

Journal Articles

Flowsheet study of the thermochemical water-splitting IS process for effective hydrogen production

Kasahara, Seiji; Kubo, Shinji; Hino, Ryutaro; Onuki, Kaoru; Nomura, Mikihiro*; Nakao, Shinichi*

Proceedings of AIChE 2005 Spring National Meeting (CD-ROM), 8 Pages, 2005/04

Japan Atomic Energy Research Institute (JAERI) has been conducting the research and development on the thermochemical water-splitting IS process for effective hydrogen production using nuclear heat of close to 1000 $$^{circ}$$C that can be supplied from High Temperature Gas-cooled Reactor (HTGR). The activity covers the studies on the process control for the continuous hydrogen production, the process improvements in the HI decomposition procedure and the preliminary screening of corrosion resistant materials of construction. Present status of the study is presented, especially, focusing on the process flowsheeting study concerning the application of membrane process for the HI processing.

Journal Articles

Development of the large-scale fine and non-thermal manufacturing technology using femtosecond, highly- efficient, and high power free-electron laser

Minehara, Eisuke

Proceedings of 28th Linear Accelerator Meeting in Japan, p.402 - 403, 2003/08

The JAERI superconducting RF linac-based free-electron laser has successfully generated 6% highly-efficient, a few hundreds of femtosecond, and several kW class high power FEL light several years ago. In the presentation, it will be reprted that the JAERI plans to develop the higher power free-electron lasers and their application to large-scale non-thermal precision manufacturing technology.

Journal Articles

Effects of process parameters of the IS process on total thermal efficiency to produce hydrogen from water

Kasahara, Seiji; Hwang, G.*; Nakajima, Hayato; Choi, H.*; Onuki, Kaoru; Nomura, Mikihiro

Journal of Chemical Engineering of Japan, 36(7), p.887 - 899, 2003/07

 Times Cited Count:66 Percentile:87.93(Engineering, Chemical)

Thermal efficiency of the IS thermochemical hydrogen production process was evaluated. Sensitivities of operation conditions (HI conversion ratio, pressure and reflux ratio at HI distillation and concentration of HI after EED) and nonidealities of the process (electric energy loss in EED, loss at heat exchangers and loss of waste heat recovery as electricity) were investigated. Concentration of HI after EED had the most significant effect of 13.3 % on thermal efficiency in operation conditions. Nonidealities had importance on thermal efficiency. Thermal efficiency was 56.8 % with optimized operation conditions and no nonidealities.

JAEA Reports

Evaluation of thermal efficiency to produce hydrogen through the IS process by thermodynamics

Nomura, Mikihiro; Kasahara, Seiji; Onuki, Kaoru

JAERI-Research 2002-039, 24 Pages, 2003/01

JAERI-Research-2002-039.pdf:1.01MB

Thermal efficiency to produce hydrogen from water through the IS process was evaluated by a viewpoint of thermodynamics. Thermal efficiency is decided by a temperature from a heat source and limited by the works calculated by the Carnot efficiency for any hydrogen production methods. The maximum thermal efficiency is 81.3% for a thermal cycle between 1123K and 733K. The thermal efficiency of the IS process was evaluated by G-T diagrams of each reactions and separation processes. The maximum value is 78.2% without considering the works for separations of acids from water. However, the effects of the works for separations on thermal efficiency are essential for the IS process, because Gibbs energies of separations of acids from water are always positive. The thermal efficiency could be changed from 53.5% to 76.6% by the calculation with or without the separation processes.

Journal Articles

Development of the compact heat exchanger for the HTGR, 2; Heat transfer and fluid characteristics test

Ishiyama, Shintaro; Muto, Yasushi; Ogata, Hiroshi*; Kamito, Yoshimi*

Nihon Genshiryoku Gakkai-Shi, 43(7), p.708 - 717, 2001/07

 Times Cited Count:3 Percentile:27.1(Nuclear Science & Technology)

no abstracts in English

JAEA Reports

General characteristics and technical subjects on helium closed cycle gas turbine

Shimomura, Hiroaki

JAERI-Research 96-034, 73 Pages, 1996/06

JAERI-Research-96-034.pdf:2.47MB

no abstracts in English

JAEA Reports

A Study on steam reforming process using nuclear heat of VHTR

*; ;

JAERI-M 90-082, 44 Pages, 1990/05

JAERI-M-90-082.pdf:1.16MB

no abstracts in English

Journal Articles

Coupling of thermochemical hydrogen production processes with an HTGR

; Shimizu, Saburo; Nakajima, Hayato; Ikezoe, Yasumasa;

Int.J.Hydrogen Energy, 9(5), p.391 - 396, 1984/00

 Times Cited Count:5 Percentile:72.66(Chemistry, Physical)

no abstracts in English

Journal Articles

The Nickel-iodine-Sulfur Process for Thermochemical hydrogen production, I; Proposal

Shimizu, Saburo; ; Ikezoe, Yasumasa; Nakajima, Hayato

Denki Kagaku Oyobi Kogyo Butsuri Kagaku, 49(11), p.699 - 704, 1981/00

no abstracts in English

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